From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 6abe3321f4b8442f5316c4d3 10.52957/2782-1900-2026-7-3-152-158 Научные статьи Scientific articles Научные статьи Synergistic and antagonistic effects in the interaction of ionic and nonionic surfactant systems Synergistic and antagonistic effects in the interaction of ionic and nonionic surfactant systems Колосова Анастасия Николаевна Kolosova Anastasiya Nikolaevna lyapisnuska@yandex.ru Терешко Анастасия Евгеньевна Tereshko Anastasiya Evgenievna tereshkoae@ystu.ru

кандидат химических наук;

candidate of chemical sciences;

 Ильин Александр Алексеевич Ilyin Aleksandr Alekseevich

доктор химических наук;

doctor of chemical sciences;

 Ярославский государственный технический университет Ярославль Россия Yaroslavl State Technical University Yaroslavl Russian Federation ООО «ЭкоЦентр» Ярославль Россия EkoTsentr, OOO Yaroslavl Russian Federation Ярославский государственный технический университет Ярославль Yaroslavl State Technical University Yaroslavl 02 10 2026 02 10 2026 7 3 152 158 22 06 2026 08 09 2026 © 2026 Колосова А.Н., Терешко А.Е., Ильин А.А. © 2026 Kolosova A.N., Tereshko A.E., Ilyin A.A. 2026 Колосова Анастасия Николаевна, Терешко Анастасия Евгеньевна, Ильин Александр Алексеевич Kolosova Anastasiya Nikolaevna, Tereshko Anastasiya Evgenievna, Ilyin Aleksandr Alekseevich Эта статья доступна по лицензии Creative Commons Attribution 4.0 International (CC BY 4.0) This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0) https://comincon.ru/en/nauka/publications/6abe3321f4b8442f5316c4d3/view

Synergistic or antagonistic effects of ionic (IS) and nonionic surfactants (NS) at various ratios was evaluated. The interaction of the surfactants was assessed by the following parameters: critical micelle concentration (CMC), surface activity, limiting adsorption at the phase interface, and molecular area. As a result, more polar nonionic surfactants (glycerol, PEG‑4000) have a stronger synergistic effect in the system with ionic surfactants. The obtained research results can be used in regulating the properties of water‑dispersion paint and coating materials.

Synergistic or antagonistic effects of ionic (IS) and nonionic surfactants (NS) at various ratios was evaluated. The interaction of the surfactants was assessed by the following parameters: critical micelle concentration (CMC), surface activity, limiting adsorption at the phase interface, and molecular area. As a result, more polar nonionic surfactants (glycerol, PEG‑4000) have a stronger synergistic effect in the system with ionic surfactants. The obtained research results can be used in regulating the properties of water‑dispersion paint and coating materials.

 surfactants ionic surfactants neoinogenic surfactants synergetic effect polarity critical concentration of micelle formation surface activity adsorption. surfactants ionic surfactants neoinogenic surfactants synergetic effect polarity critical concentration of micelle formation surface activity adsorption. The study was performed within the framework of the project ‘Modification of paint and varnish materials do not contain volatile organic compounds to improve technological and operational properties’ under the YSTU development program as part of participation in the Priority 2030 program of the Ministry of Education and Science of the Russian Federation in 2026.

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