The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method

Mikhail Soloviev; Viktor Kablov; Olga Solovyeva; Sergey Shulmin; Elizaveta Orlova

doi:10.52957/27821900_2022_04_71

UDC

678 544.3

THE CALCULATION OF SOLUBILITY PARAMETERS OF BUTADIENE NITRILE RUBBERS BY THE GROUP ADDITIVITY METHOD The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Pages 71–79 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/27821900_2022_04_71

Received: 21.11.2022 Accepted: 09.12.2022 Published: 23.12.2022 Language of publication: ENG

Authors

Mikhail Soloviev

ORCID

Viktor Kablov

ORCID SPIN

Olga Solovyeva

Sergey Shulmin

Elizaveta Orlova

Mikhail Soloviev

Academic degree: doctor of physical and mathematical sciences

Yaroslavskiy gosudarstvennyy tehnicheskiy universitet professor · kafedra Informacionnye sistemy i tehnologii · Russian Federation

ORCID

Viktor Kablov

Academic degree: doctor of technical sciences

Volzhsky Polytechnic Institute, branch of the Volgograd State Technical University Professor · department «Chemical technology of polymers and industrial ecology»

ORCID SPIN

Olga Solovyeva

Academic degree: candidate of technical sciences

Yaroslavl State Technical University Associate Professor

Sergey Shulmin

Yaroslavl State Technical University

Elizaveta Orlova

Volzhsky Polytechnic Institute, branch of the Volgograd State Technical University

ABSTRACT

Butadiene Nitrile Rubber (BNR) is a special purpose elastomer with an increased resistance to aliphatic hydrocarbon solvents, oils, and fuels. Depending on the monomer ratio of the butadiene-nitrile copolymers, their compatibility with different types of solvents and plasticisers varies considerably. In additional, BNRs with carboxyl, hydroxyl and hydrogenated BNRs are industrially available. The purpose of the study was to calculate the solubility parameters of different compositions of BNRs copolymers, hydrogenated BNRs, and rubbers with hydroxyl and carboxyl groups. We calculated the increments of the functional groups of copolymers under study and the molecular attraction by the Small constants. The calculations based on the processing of reference data on the enthalpies of evaporation and molar volume of aliphatic and aromatic hydrocarbons, nitriles, acids, alcohols, and esters. Also we used the increments obtained to calculate three dimensional solubility parameters of the copolymers as well as the dependencies of the change in Gibbs free energy at mixing on the solvent volume fraction for the two types of solvents.

KEYWORDS

butadiene nitrile rubbers, solubility parameters, group additivity method

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Soloviev M. E., Kablov V. F., Solovyeva O. Y., Shulmin S. N., Orlova E. N. The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method // From Chemistry Towards Technology Step-By-Step. 2022. no. 4. pp. 71-79. DOI: https://doi.org/10.52957/27821900_2022_04_71. (Date of access 07.09.2026).

MLA

Mikhail Soloviev, Kablov V. F., Solovyeva O. Y., Shulmin S. N., Orlova E. N.. "The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method." From Chemistry Towards Technology Step-By-Step 3.4 (2022): 71-79. DOI: https://doi.org/10.52957/27821900_2022_04_71.

APA

Soloviev M. E., Kablov V. F., Solovyeva O. Y., Shulmin S. N., Orlova E. N. (2022). The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method. From Chemistry Towards Technology Step-By-Step, 3(4), 71-79. https://doi.org/10.52957/27821900_2022_04_71

Chicago

Mikhail Soloviev, Kablov V. F., Solovyeva O. Y., Shulmin S. N., Orlova E. N.. "The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method." From Chemistry Towards Technology Step-By-Step 3, no. 4 (2022): 71-79. https://doi.org/10.52957/27821900_2022_04_71.

WIKI

{{cite journal | author = Soloviev M. E., Kablov V. F., Solovyeva O. Y., Shulmin S. N., Orlova E. N. | title = The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method | journal = From Chemistry Towards Technology Step-By-Step | year = 2022 | volume = 3 | issue = 4 | pages = 71-79 | doi = 10.52957/27821900_2022_04_71 }}

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THE CALCULATION OF SOLUBILITY PARAMETERS OF BUTADIENE NITRILE RUBBERS BY THE GROUP ADDITIVITY METHOD The calculation of solubility parameters of butadiene nitrile rubbers by the group additivity method

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