Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine

Tatyana Nokoforova; Daria Vokurova; Artemiy Sofronov

doi:10.52957/27821900_2022_03_17

UDC 544.7

EXTRACTION OF COPPER IONS BY A SORBENT BASED ON FLAX FIBER MODIFIED WITH L-ARGININE Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 3, Issue 3 · Pages 17–26 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/27821900_2022_03_17

Received: 01.07.2022 Accepted: 12.09.2022 Published: 23.09.2022

Authors

Tatyana Nokoforova

Daria Vokurova

Artemiy Sofronov

Tatyana Nokoforova

Academic degree: doctor of chemical sciences

Science rang: docent

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Daria Vokurova

Ivanovo State University of Chemistry and Technology Ivanovo

Artemiy Sofronov

Ivanovo State University of Chemistry and Technology Ivanovo

ABSTRACT

This paper studies the process of Cu(II) ions extraction from aqueous solutions by cellulose-containing sorbents: native and modified by L-arginine flax fiber. We processed the experimental kinetic curves of copper ion sorption by pseudo-first and pseudo-second order models and obtain a high correlation coefficient (0.99) when used a pseudo-second order kinetics model. The results of the treatment of the sorption isotherms according to the Langmuir model indicate the model capability for the description of the process of copper ions sorption by cellulose sorbents. As a result of two-stage chemical modification through the oxidation stage of linen fibre with sodium periodate and subsequent modification with L-arginine, we obtain a new sorbent, which can be used to purify aqueous solutions from heavy metal ions. The paper also presents SEM images and elemental analysis of original and modified flax fibre samples. The infrared spectra confirms the changes occurred in the linen fibre during modification. The obtained sorbent significantly surpasses the native linen fibre in its sorption characteristics, as evidenced by the values of the ultimate sorption capacity.

KEYWORDS

flax fibre, modification, L-arginine, sodium metaperiodate, sorption, Cu(II) ions

Funding

This work was supported by Ivanovo State University of Chemistry and Technology, Ivanovo, Russia Centre for the Collective Use of Scientific Equipment (the Russian Ministry of Education and Science, Agreement No. 075-15-2021-671). The work was carried out within the framework of the state research assignment. Theme № FZZW-2020-0010.

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GOST

Nokoforova T. E., Vokurova D. A., Sofronov A. R. Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine // From Chemistry Towards Technology Step-By-Step. 2024. no. 3. pp. 17-26. DOI: https://doi.org/10.52957/27821900_2022_03_17. (Date of access 23.10.2026).

MLA

Tatyana Nokoforova, Vokurova D. A., Sofronov A. R.. "Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine." From Chemistry Towards Technology Step-By-Step 3.3 (2024): 17-26. DOI: https://doi.org/10.52957/27821900_2022_03_17.

APA

Nokoforova T. E., Vokurova D. A., Sofronov A. R. (2024). Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine. From Chemistry Towards Technology Step-By-Step, 3(3), 17-26. https://doi.org/10.52957/27821900_2022_03_17

Chicago

Tatyana Nokoforova, Vokurova D. A., Sofronov A. R.. "Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine." From Chemistry Towards Technology Step-By-Step 3, no. 3 (2024): 17-26. https://doi.org/10.52957/27821900_2022_03_17.

WIKI

{{cite journal | author = Nokoforova T. E., Vokurova D. A., Sofronov A. R. | title = Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 3 | issue = 3 | pages = 17-26 | doi = 10.52957/27821900_2022_03_17 }}

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EXTRACTION OF COPPER IONS BY A SORBENT BASED ON FLAX FIBER MODIFIED WITH L-ARGININE Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine

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