from 01.01.1974 until now
Yaroslavl, Yaroslavl, Russian Federation
Volgograd, Volgograd, Russian Federation
Moscow, Moscow, Russian Federation
Volzhskiy, Vologda, Russian Federation
Primenitel'no k processu piroliza iznoshennyh shin i othodov rezino-tehnicheskih izdeliy v promyshlennom reaktore privedena kineticheskaya model' termodestrukcii polimera. Vypolneny kvantovo-himicheskie raschety izmeneniya termodinamicheskih funkciy pri veroyatnyh himicheskih reakciyah destrukcii setchatyh elastomerov. V kachestve produktov reakcii rassmotrena tverdaya frakciya (tehnicheskiy uglerod i othody metalla) i parogazovaya smes', razdelyaemaya na tri frakcii uglevodorodov. Pri opisanii kinetiki destrukcii rezin ispol'zovana formal'naya kineticheskaya shema, otrazhayuschaya mehanizm processa kak sovokupnost' radikal'no-cepnyh reakciy destrukcii polimera. Kazhdoy frakcii uglevodorodov sootvetstvuet opredelennyy nabor kineticheskih konstant, temperaturnye zavisimosti kotoryh prinyaty arreniusovskimi. Udovletvoritel'noe soglasie poluchennyh raschetnyh termogravimetricheskih zavisimostey s eksperimental'nymi dannymi razlichnyh avtorov pozvolilo approksimirovat' krivye termodestrukcii rezin krivymi, harakterizuyuschimi kauchuki obschego naznacheniya.
iznoshennye shiny, rezinovye othody, piroliz, kineticheskaya model', kvantovo-himicheskiy raschet
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