from 01.01.1974 until now
Yaroslavl, Yaroslavl, Russian Federation
Volgograd, Volgograd, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
student
Yaroslavl, Yaroslavl, Russian Federation
student
Volzhskiy, Volgograd, Russian Federation
UDK 544.3 Химическая термодинамика
Butadien-nitril'nye kauchuki (BNK) otnosyatsya k elastomeram special'nogo naznacheniya i otlichayutsya povyshennoy stoykost'yu k alifaticheskim uglevodorodnym rastvoritelyam, maslam, toplivu. V zavisimosti ot sootnosheniya monomerov v butadien-nitril'nyh sopolimerah sovmestimost' ih s razlichnymi tipami rastvoriteley i plastifikatorov suschestvenno izmenyaetsya. Krome togo, promyshlennost'yu vypuskayutsya BNK s funkcional'nymi gruppami: karboksil'nymi, gidroksil'nymi, a takzhe gidrirovannye BNK. Cel'yu nastoyaschey raboty yavilsya raschet parametrov rastvorimosti sopolimerov BNK razlichnogo sostava, gidrirovannyh BNK i kauchukov s gidroksil'nymi i karboksil'nymi gruppami. Na osnovanii obrabotki spravochnyh dannyh po ental'piyam ispareniya i mol'nomu ob'emu organicheskih soedineniy iz klassov alifaticheskih i aromaticheskih uglevodorodov, nitrilov, kislot, spirtov i efirov vychisleny inkrementy funkcional'nyh grupp, prisutstvuyuschih v celevyh sopolimerah, i konstanty molekulyarnogo prityazheniya Smolla. Poluchennye inkrementy ispol'zovany dlya rascheta trehmernyh parametrov rastvorimosti sopolimerov, a takzhe zavisimostey izmeneniya svobodnoy energii Gibbsa pri smeshenii ot ob'emnoy doli rastvoritelya dlya dvuh tipov rastvoriteley.
butadien-nitril'nye kauchuki, parametry rastvorimosti, metod additivno-gruppovyh vkladov
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