Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
from 01.01.1974 until now
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
The paper examines the classification of de-icing agents and identifies the most commonly used additives in road maintenance. The article describes the mechanism for producing a combined acetate de-icing agent from sealant production wastes. Experiments shows total removing of ice by combined acetate reagent in 30 minutes. Also the study investigates the effect of de-icing agents on galvanised automobile parts. The interaction between the de-icing agent and the metal automobile parts proceeds through the anodic and cathodic oxidation-reduction reactions. The paper dwells on electrochemical corrosion underlying chemistry. In order to evaluate the effect of antifreeze additives on the electrochemical corrosion of zinc coating the authors present the results of the quantum-chemical calculations of zinc ions intermolecular complexes energies formations with water molecules and antifreeze additives. We made the conclusions by the results of the scientific work. According to the results, sodium phormiate can be classified as a gentle de-icing agent, characterising by low corrosive effect in a humid environment. The better result was shown by the combined de-icing agent in a dry environment. The maximum corrosion rate of the zinc coating in a wet environment is higher than in a dry one.
De-icing agents, technical salt, urea, sodium phormiate, electrochemical corrosion, underlying chemistry
1. Podol'skiy, V.P., Samodurova T.V., Fedorova Yu.V. Ekologicheskie aspekty zimnego soderzhaniya dorog. Voronezh: Izd-vo Voronezh. gos. arhitektur.-stroit. akad., 2000. 152 s.
2. Azovtseva N.A., Smagin A.V. Dynamics of physical and physicochemical properties of urban soils under the effect of ice-melting salts // Eurasian Soil Science. 2018. Vol. 51, no. 1. P. 120-129. DOI:https://doi.org/10.1134/S1064229318010027
3. Bespamyatnov G.P., Krotov Yu.A. Predel'no dopustimye koncentracii himicheskih veschestv v okruzhayuschey srede. L.: Himiya, 2007. 528 s.
4. Privalova N.M., Procay A.A., Litvinenko Yu.F., Marchenko L.A, Pan'kov V.A. Opredelenie fitotoksichnosti metodom prorostkov // Uspehi sovremennogo estestvoznaniya. 2006. № 10. S. 45-45.
5. Chesnokova S.M., Chugay N.V. Biologicheskie metody ocenki kachestva ob'ektov okruzhayuschey sredy. V 2 ch. Ch. 2. Metody biotestirovaniya: ucheb. posobie. Vladimir: Izd-vo Vladim. gos. un-t, 2008. 92 s.
6. Volkova I.N., Kondakova G.V. Ekologicheskoe pochvovedenie: Laboratornye zanyatiya dlya studentov-ekologov (bakalavrov): Metod. ukazaniya. Izd-vo Yarosl. gos. un-t, 2002. 35 s.
7. Rukovodstvo po bor'be s zimney skol'zkost'yu na avtomobil'nyh dorogah. Utverzhdeno Rasporyazheniem Mintransa RF ot 16 iyunya 2003 g. № OS-548-r.
8. Kalaev R.E., Nikitinskaya M.A., Markelova N.L. Bor'ba s gololedom v Rossii i za rubezhom // Sem'desyat pervaya vserossiyskaya nauchno-tehnicheskaya konferenciya studentov, magistrantov i aspirantov vysshih uchebnyh zavedeniy s mezhdunarodnym uchastiem. 18 aprelya 2018 g. Yaroslavl': sb. materialov. konf. V 3 ch. Ch. 1 [Elektronnyy resurs]. Yaroslavl': Izdat. dom YaGTU, 2018. 1 elektron. opt. disk (CD-ROM). S. 747-750.
9. Kalaev R.E., Nikitinskaya M.A., Kalaeva S.Z. , Markelova N.L. Vliyanie antigololednyh reagentov na okruzhayuschuyu sredu // Innovacionnye puti resheniya aktual'nyh problem prirodopol'zovaniya i zaschity okruzhayuschey sred. Sb. dokl. mezhdunar. nauch.-tehn. konf. Alushta. 4–8 iyunya. 2018 g. Belgorod: Izd-vo Belgor. gos. tehnol. un-t, 2018. S. 230-234.
10. Kalaev R.E., Nikitinskaya M.A., Kalaeva S.Z., Markelova N.L. Vliyanie karbamida i formiata natriya na komponenty biosfery // Ekologiya Rossii i sopredel'nyh territoriy: Materialy 23 Mezhdunarodnoy ekologicheskoy studencheskoy konferencii; Novosibirskiy gosudarstvennyy universitet. Novosibirsk: Izd-vo IPC NGU, 2018. S. 14.
11. Frolova E.A., Kondakov D.F., Orlova V.T., Danilov V.P., Avdyushkina L.I., Bykov A.V. Design of deicing reagents based on alkali and alkaline-earth metals and ammonium formates, acetates, and nitrates // Theoretical Foundations of Chemical Engineering. 2013. Vol. 47, no. 4. R. 422-427. DOI:https://doi.org/10.1134/S0040579513040076.
12. Szklarek S., Górecka A., Wojtal-Frankiewicz A. The effects of road salt on freshwater ecosystems and solutions for mitigating chloride pollution - a review // The Science of the Total Environment. 2022. Vol. 805. P. 150289. DOI:https://doi.org/10.1016/j.scitotenv.2021.150289.
13. Gomatin N.A. Fiziko-himicheskie osnovy korrozii cinkovyh pokrytiy // International Journal of Humanities and Natural Sciences. 2019. Vol. 4-2. P. 32-35. DOI:https://doi.org/10.24411/2500-1000-2019-10746.
14. Petrova L.G., Timofeeva G.Yu., Demin P.E., Kosachev A.V. Osnovy elektrohimicheskoy korrozii metallov i splavov: uchebnoe posobie. M.: MADI, 2016. 148 s.
15. Solov'ev M.E., Dmitriev K.E. Komp'yuternoe modelirovanie v himii: uchebnoe posobie. Yaroslavl': Izd-vo YaGTU, 2021. 256 s.
16. Neese F. The ORCA program system. Wiley Interdiscip. Rev.: Comput. Mol. Sci., 2012. Vol. 2, no. 1. P. 73 78.
17. Neese F. Software update: the ORCA program system, version 4.0 // Wiley Interdiscip. Rev.: Comput. Mol. Sci., 2017. Vol. 8, no. 1. P. 1327.
18. Korolev G.V., Il'in A.A., Solov'ev M.E., Mogilevich M.M., Evplonova E.S. Komp'yuternoe modelirovanie associativnyh struktur efirov akrilovogo ryada // Vysokomolekulyarnye soedineniya. Seriya A. 2001. T. 43, № 10. S. 1822-1827.
19. Korolev G.V., Il'in A.A., Solov'ev M.E., Srybnyy A.V., Mogilevich M.M., Evplonova E.S. Komp'yuternoe modelirovanie stroeniya i temperaturnoy stabil'nosti associatov vysshih alkil(met)akrilatov // Vysokomolekulyarnye soedineniya. Seriya A. 2002. T. 44, № 11. S. 1947-1954.
20. Korolev G.V., Il'in A.A., Solov'ev M.E., Mogilevich M.M., Srybnyy A.V., Evplonova E.S. Komp'yuternoe modelirovanie stroeniya i temperaturnoy stabil'nosti polimer-monomernyh associatov nekotoryh vysshih n-alkil (met)akrilatov // Vysokomolekulyarnye soedineniya. Seriya B. 2005. T. 47. № 1. S. 94-98.
21. Solov'ev M.E. Eksperimental'no-statisticheskie metody v himiko-tehnologicheskih issledovaniyah s ispol'zovaniem programmnyh sredstv Open Source: uchebnoe posobie. Yaroslavl': Izd-vo YaGTU, 2012. 263 s.