ANALYSIS, SYSTEMATIZATION AND PREDICTION OF THERMODYNAMIC CHARACTERISTICS OF ORGANIC COMPOUNDS AND THEIR SOLUTIONS BASED ON THE ADDITIVE-GROUP METHOD
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Abstract (English):
The article summarizes the literature data and the results of the description, systematization and prediction obtained by the authors within the framework of the additive-group approach of the physicochemical properties of organic substances of various classes and their solutions, as well as the parameters of the fire hazard of liquids.

Keywords:
additive-group method, organic compounds, solutions, physicochemical properties, thermodynamic characteristics, parameters of fire hazard, flash point
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References

1. Benson S. Thermochemical kinetics. Moscow: Mir, 1971. 308 p. (in Russian).

2. Tatevskii V.M. Theory of physical and chemical properties of molecules and substances. Moscow: Izd-vo Mosk. un-ta, 1987. 239 p. (in Russian).

3. Tatevskii V.M. Basics of classical theory of molecular structure. Moscow: MSU Publ. House, 1971. 90 p. (in Russian).

4. Tatevskii V.M. Classical theory of molecular structure and quantum mechanics. Moscow, 1973. 516 p. (in Russian).

5. Tatevskii V.M. The structure of molecules. Moscow, 1971. 512 p. (in Russian).

6. Lebedev Yu.A., Miroshnichenko E.A. Thermochemistry of vaporization of organic substances. Moscow: Nauka, 1981. 216 p. (in Russian).

7. Ribeiro da Silva M.A.V. Thermochemistry of substituted pyridines and analogous heterocycles: the enthalpic increments for a group additivity scheme. Pure and Appl. Chem. 1999. Vol. 71. N 7. P. 1257-1265.

8. Kizin A.N., Dvorkin P.L., Ryzhova G.L., Lebedev Yu.A. Parameters for calculating the molar volume and density of liquid organic substances. Izv. AN SSSR. 1986. N 2. P. 372-375 (in Russian).

9. Dvorkin P.L., Ryzhova G.L., Lebedev Yu.A. Parameters for calculating the enthalpies of formation of organic compounds in the liquid state. Izv. AN SSSR. 1983. N 5. P. 1101 (in Russian).

10. Kizin A.N., Orlov Yu.D., Lebedev Yu.A. Development of numerical thermochemical data base and methods for prediction of organic substances and radicals properties. Problemy khimii rastvorov i tekhnologii zhidkofaznykh materialov. Ivanovo, 2001. P. 73-81 (in Russian).

11. Orlov Yu.D., Lebedev Yu.A. Databases and methods for prediction of thermodynamic properties of organic radicals. Zhurnal khimii termodinamiki i termokhimii. 1992. Vol. 1. N 2. P. 131-142 (in Russian).

12. Inglese A., Mavelli F., De Lisi R., Milioto S. Partial Molar Volumes of Alkanes, Alcohols, and Glycols in Polar Organic Solvents. J. Solut. Chem. 1997. Vol. 10. N 3. P. 319-336. P. 563-595.

13. Nishimura No., Tanaka T., Motoyama T. Additivity of the partial molar volumes of organic compounds. Can. J. Chem. 1987. Vol. 65. N 9. P. 2248-2253.

14. Stillinger F.H. Structure in aqueous solutions of nonpolar solutes from standpoint of scaled-particle theory. J. Solut. Chem. 1973. Vol. 2. N 2-3. P. 141-158.

15. Terasawa S., Itsuki H., Arakawa S. Contribution of hydrogen bond to the partial molar volumes of nonionic solutes in water. J. Phys. Chem. 1975. Vol. 79. N 22. P. 2345-2351.

16. Zielenkiewicz A., Perlovich G.L., Nikitina G.E., Golubchicov O.A. Volumetric properties of methyl, tert-butyl, and alkoxy derivates of tetraphenylporphyrin in benzene solution. J. Solut. Chem. 1997. Vol. 26. N 7. P. 663-680.

17. Edward J.T., Farrell P.G., Shahidi F. Partial molar volumes of organic compounds in carbon tetrachloride. 1. Alkanes. Conformotional effect. J. Phys. Chem. 1978. Vol. 82. N 21. P. 2310-2313.

18. Shahidi F., Farrell P.G.,.Edward J.T. Partial molar volumes of organic compounds in carbon tetrachloride. 2. Haloalkanes. J. Phys. Chem. 1979. Vol. 83. N 3. P. 419-422.

19. Cabani S., Gianni P. Thermodynamic functions of hydratation of saturated uncharged organic compounds. Free energies, enthalpies and entropies at 25o C. J. Chem. Soc. Faraday Trans. I. 1979. Vol. 75. P. 1184-1195.

20. Cabani S., Gianni P., Mollica V., Lepori L. Group contributions to the thermodynamics properties of non-ionic organic solutes in dilute aqueous solution. J. Solut. Chem. 1981. Vol. 10. P. 563-595.

21. Rusanov A.I. Micelle formation in surfactant solutions. St. Petersburg: Khimiya, 1992. 280 p. (in Russian).

22. Devies J.T., Rideal E.K. Interfacial Phenomena. N.Y.: Academic Press, 1963. 480 p.

23. Belousov V.P. Development and application of the mixing enthalpy method to study the intermolecular interactions in the solutions of non-electrolytes: dissertation, Dr. Chem. Leningrad: 1977. 374 p. (in Russian).

24. Arnett E.M., Kover W.B., Carter J.V. Heat capacities of organic compounds in solution. I. Low molecular weight alcohols in water. J. Am. Chem. Soc. 1969. Vol. 91. N 15. P. 4028-4034.

25. Hill D.J.T., White L.R. The enthalpies of solution of hexan-1-ol and heptan-1-ol in water. Austr. J. Chem. 1974. Vol. 27. N 9. P. 1905-1916.

26. Cabani S., Conti C., Mollica V., Lepori I. Thermodynamic study of dilute aqueous solutions of organic compounds. Part 5. Openchain saturated bifunctional compounds. J. Chem. Soc. Faraday Trans. I. 1978. Vol. 74. N 11. P. 2667-2671.

27. Konicek J., Wadso I. Thermochemical properties of some carboxylic acids, amines and No-substituted amides in aqueous solution. Acta Chem. Scand. 1971. Vol. 25. P. 1541-1546.

28. Hallen D., Nilsson S.-O., Rotschield W., Wadsö I. Enthalpies and heat capacities for n-alkan-1-ols in water and heavy water. J. Chem. Thermodyn. 1986. Vol. 18. P. 429-434.

29. Joness P.M., Arnett E.M. Progress in physical organic chemistry. Vol. 11 / Ed. A. Streitweiser. N.Y.: J. Wiley, 1974. P. 263-322.

30. Gross R.F., McTigue P.T. An analysis of the thermodynamics of transfer of polar non-electrolytes from water to aqueous concentrated salt solutions. Austr. J. Chem. 1977. Vol. 30. P. 597-2612.

31. Nichols No., Skold R., Spink C., Wadso I. Thermochemistry of solutions of biochemical model compounds: vi alpha, omega-dicarboxylic acids, -diamines, and -diols in aqueous solution. J. Chem. Thermodyn. 1976. Vol. 8. N 10. P. 993-999.

32. Corkil J.M., Goodman J.P., Tate J. Heats of solution of substituted n-alkanes in water. J. Trans. Faraday Soc. 1969. Vol. 65. N 7. P.1742-1748.

33. Cox B.G. Free energies, enthalpies, and entropies of transfer of non-electrolutes from water to mixtures of water and dimethyl sulfoxide, water and acetonitrile, and water and dioxane. J. Chem. Soc. Perkin Trans. II. 1973. N 5. P. 605-610.

34. Pury R., Lucas M., Barberi P. Ėtude des grandeurs thermodynamicues de transfert l`une serie de cetones de l`etat gazeux a l`etat dilute dans l`eau. J. chim. phys. 1978. Vol. 75. N 6. P. 575-577.

35. Della Gatta G., Stradella L., Venturello P. Enthalpies of solvation in cyclohexane and in water for homologous aliphatic ketones and esters. J. Solut. Chem. 1981. Vol. 10. N 3. P. 209-220.

36. Belousov V.P., Panov M.Yu. Thermodynamics of aqueous solutions of non-electrolytes. Leningrad: Khimiya, 1983. 264 p. (in Russian).

37. Batov, D.V. Solubilization ntalpies of non-electrolytes and intermolecular interactions in their aqueous, alco-holic and aqueous-alcoholic solutions: dissertation, PhD. Ivanovo, IKhNR AN SSSR, 1987. 162 p. (in Russian).

38. Dec S.F., Gill S.J. Enthalpies of aqueous solutions of noble gases at 25o C. J. Solut. Chem. 1985. Vol. 14. N 6. P. 417-429.

39. Zielenkiewicz A., Wszelaka-Rjlik G., Poznanski J., Zielenkiewicz W. Thermochemistry of aqueous solutions of alkylated nucleic acid bases. X. Enthalpies of hydration of citosine and some methylated, hydroxy and methoxy derivates of citisine. J. Solut. Chem. 1998. Vol. 27. N 3. P. 235-244.

40. Krishnan C.V., Friedman H.L. Solvation Enthalpies of Hydrocarbones and Normal Alcohols in Highly Polar Solvents. J. Phys. Chem. 1971. Vol. 75. N 23. P. 3598-3605.

41. Fuchs R., Stephenson W.K. Enthalpies of Transfer of Alkane Solutes from the Vapor State to Organic Solvents. Can. J. Chem. 1985. Vol. 63. N 2. P. 349-352.

42. Solomonov B.N., Konovalov A.I. Thermochemistry of solvation of organic non-electrolytes. Uspekhi khimii. 1991. Vol. 60. N 1. P. 45-68 (in Russian).

43. Antonova O.A., Batov D.V., Korolev V.P. Solvation enthalpies of hydrocarbons in aqueous-alcoholic solvents. ZhOKh. 1993. Vol. 63. N 10. P. 2200-2205 (in Russian).

44. Heuvelsland W J. M., De Visser C., Somsen G. Hydrophobic hydration of tetraalkylammonium bromides in mixture of water and some aprotic solvent. J. Phys. Chem. 1978. Vol. 82. N 1. P. 29-32.

45. Rocha F., Bastos M. Enthalpies of solution of n-alcohols in formamide and ethylene glycol. J. Solut. Chem. 1997. Vol. 26. N 10. P. 989-996.

46. Stephenson W.K., Fuchs R. Enthalpies of Interaction of Ketones with Organic Solvents. Can. J. Chem. 1985. Vol. 63. N 2. P. 336-341.

47. Kent H.E., Lilley T.H., Milburn P.J., Bloemendal M., Somsen G. Interactions between terminalli substituted amino acids in an aqueous and a non-aqueous environment. Enthalpic interaction coefficients in water and N,N-dimethylformamide at 25oC. J. Solut. Chem. 1985. Vol. 14. P. 101-116.

48. Solomonov B.N., Konovalov A.I. A new approach to the analysis of enthalpies of solvation of organic com-pounds-non-electrolytes. ZhOKh. 1985. Vol. 55. N 11. P. 2529-2546 (in Russian).

49. Ben-Naim A., Marcus Y. Solvation thermodynamics of the nonionic solutes. J. Chem. Phys. 1984. Vol. 81. N 4. P. 2016-2027.

50. Marcus Y. Ion Solvation. N.Y.: Wiley, 1985. 306 p.

51. Abramzon A.A., Slavin A.A. On the additivity of intermolecular interaction energy of organic compounds according to their constituent groups. ZhFKh. 1970. Vol. 44. N 3. P. 564-569 (in Russian).

52. Abramzon A.A. Surfactants. Leningrad: Khimiya, 1976. 414 p. (in Russian).

53. Korolev G.V., Il'in A.A., Sizov E.A., Solov'ev M.E., Mogilevich M.M. Increments of enthalpies of evaporation of organic compounds. ZhOKh. 2000. Vol. 70. N 7. P. 1088-1091 (in Russian).

54. Majer V., Svoboda V. Enthalpies of Vaporisation of organic Compounds. Oxford: London, 1985. 300 p.

55. Bondi A. Van-der-Waals Volumes and Radii. J. Phys. Chem. 1964. Vol. 68. N 3. P. 441-451.

56. Solomonov B.N., Novikov V.B., Konovalov A.I. Estimation of intermolecular interaction energies using dis-solution enthalpy data. DAN SSSR. 1980. Vol. 255. P. 1181-1184 (in Russian).

57. Solomonov B.N., Konovalov A.I., Novikov V.B., Gorbachuk V.V., Neklyudov S.A. Solvation of organic compounds. Molecular refraction dipole momentum and enthalpy of solvation. ZhOKh. 1984. Vol. 54. P. 1622-1632 (in Russian).

58. Solomonov B.N., Konovalov A.I., Novikov V.B., Gorbachuk V.V., Neklyudov S.A. Solvation of organic compounds. Determination of the enthalpy of the specific interaction of the dissolved substance with the solvent. ZhOKh. 1985. Vol. 55. N 9. P. 1889-1906 (in Russian),

59. Fuchs R., Rodewald R.F. Aromatic substituted group enthalpies of transfer from methanol to N,N-dimethyl-formamide. J. Am. Chem. Soc. 1973. Vol. 95. N 18. P. 5897-5900.

60. Smirnov V.I., Krestov G.A. Thermochemical characterization of solvation of mono- and polycyclic aromatic hydrocarbons and their derivatives in non-aqueous media. Zhurn. khim. termodinamiki i termokhimii. 1993. Vol. 2. N 1. P. 1-24 (in Russian).

61. Smirnov V.I., Krestov G.A. Solvation of some polycyclic aromatic hydrocarbons and their derivatives in non-aqueous media. Proceedings of the III Russian Conference Khimiya i Primenenie Nevodnykh Rastvorov. Ivanovo, 1993. P. 149 (in Russian).

62. Smirnov V.I., Krestov G.A. Peculiarities of aromatic hydrocarbons solvation in non-aqueous media. Proceedings of the III Russian Conference Khimiya i Primenenie Nevodnykh Rastvorov. Ivanovo, 1993. P. 23-26 (in Russian).

63. Stephenson W.K., Fuchs R. Enthalpies of interaction of aromatic solutes with Organic Solvents. Canad. J. Chem. 1985. Vol. 63. P. 2529-2534.

64. Smirnov V.I., Perlovich G.L., Fridman A.Ya. Thermochemical characteristics of the effects of the functional substituents of 1,4-dioxybenzene and their relation to the Gammet constants. Proceedings of the IV All-Russian Conference Problemy Solvatatsii i Kompleksoobrazovaniya v Rastvorakh. Ivanovo, 1991. P. 145 (in Russian)/

65. Savage J.J., Wood R.H. Enthalpy of dilution of aqueous mixtures of amides, sugars, urea, ethylene glycol, and pentaerythritol at 25°C: Enthalpy of interaction of the hydrocarbon, amide, and hydroxyl functional groups in dilute aqueous solutions. J. Solut. Chem. 1976. Vol. 5. P. 733-750.

66. Cifra P., Romanov A. Group contribution and hydrophobic hydration. J. Solut. Chem. 1984. Vol. 13. N 6. P. 431-441.

67. Cheek P.J., Lilley T.No. The enthalpies of interaction of some amides with urea in water at 25 0C. J. Chem. Soc., Faraday Trans. I. 1988. Vol. 84. N 6. P. 1927-1940.

68. Gallardo-Jimenez M.A., Lilley T.H. Enthalpies of interaction of some alkali metal halides with No-methyla-cetamide and with N,N-dimethylformamide in water at 25oC. J. Chem. Soc., Faraday Trans. I. 1989. Vol. 85. N 9. P. 2909-2916.

69. Kusano K., Suurkuusk I., Wadsö I. Thermochemistry of Solutions of Biochemical Model Compounds 2. Alkox-yethanols and 1,2-Dialkoxyethanes in Water. J. Chem. Thermodyn. 1973. Vol. 5. N 5. P. 757-767.

70. Dec S.F., Gill S.J. Heats of solution of gaseous hydrocarbons in water at 25o C. J. Solut. Chem. 1984. Vol. 13. N 1. P. 27-41.

71. Dec S.F., Gill S.J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35o C. J. Solut. Chem. 1985. Vol. 14. N 12. P. 827-836.

72. Krestov G.A., Vinogradov V.I., Barbetova L.P. Thermodynamics of dissolution of nitrogen and oxygen in aqueous solutions of polyatomic alcohols. Termodinamika i stroenie rastvorov. Ivanovo: IKhTI, 1980. P. 94-102 (in Russian).

73. Cabani S., Conti G., Mollica V., Lepori L. Thermodynamic study of dilute aqueous solutions of organic com-pounds. Part 4. Cyclic and straight chain secondary alcohols. J. Chem. Soc. Faraday Trans. I. 1975. Vol. 71. N 10. P. 1943-1952.

74. Knauth P., Sabbah R. Energetique des liaisons intra- et intermoleculaires dans la serie des -alcanediols. I : etude calorimetrique des enthalpies de vaporisation a 298.15 K. Bull. Soc. Chim. Fr. 1988. P. 834-836.

75. Knauth P., Sabbah R. Energetics of inter- and intramolecular bonds in alkanediols. IV. The thermochemical study of 1,2-alkanediols at 298.15 K. Thermochim. Acta. 1990. Vol. 164. P. 145-152.

76. De Visser C., Somsen G. Hydrophobic interaction in mixtures DMF – Water. J. Phys. Chem. 1974. Vol. 78. N 17. P. 1719-1722.

77. Batov D.V. Thermochemistry of organic non-electrolyte solutions in mixed solvents: dissertation, Dr. Chem. Ivanovo. 2002. 387 p. (in Russian).

78. Manin N.G., Zaichikov A.M. Thermochemical study of solvation of aliphatic carboxylic acid amides in aqueous formamide solutions. ZhOKh. 2001. Vol. 71. N 5. P. 726-735 (in Russian).

79. Taniewska-Osinska S., Jozwiak M. Calorimetric investigations of solution of NaI, KI, NaCl, KCl and C6H5NH2 in xPO{No(CH3)2}3 + (1-x)H2O at 298.15 K. J. Chem. Thermodyn. 1986. Vol. 18. N 4. P. 339-350.

80. Manin N.G., Antonova O.A., Kustov A.V., Korolev V.P. Thermochemistry of dissolution of aniline in mix-tures of water with methyl and tert-butyl alcohols. Izv. Akad. nauk. Ser. khim. 1998. N 12. P. 2471-2477 (in Russian).

81. Krestov G.A., Korolev V.P., Batov D.V. Differential effect of substitution of protium by deuterium on the properties of solvents. DAN SSSR. 1987. Vol. 293. N 4. P. 882-883 (in Russian).

82. Lyashchenko A.K., Kharkin V.S., Lileev A.S., Goncharov V.S. Dielectric relaxation and structural changes in aqueous formamide solutions. ZhFKh. 1992. Vol. 66. N 8. P. 2256-2261 (in Russian).

83. Devyatkov N.D., Betskii O.V., Zavizion V.A., Kudryashova V.A., Khurgin Yu.I. Electromagnetic radiation absorption of MM wavelength range and negative hydration in aqueous solutions of urea. DAN SSSR. 1982. Vol. 264. N 6. P. 1409-1411 (in Russian).

84. Arnett E.M. Quantitative comparison of weak organic bases. Sovremennye problemy fizicheskoi organicheskoi khimii. Moscow: Mir, 1967. P. 195-341 (in Russian).

85. Kessler Yu.M., Fomicheva P.R., Alpatova N.M. Some physical and structural characteristics of hexa-methylphosphotriamide. ZhSKh. 1972. N 3. P. 517-519 (in Russian).

86. Suri S.K., Spitzer J.J., Wood R.H., Abel E.G., Thompson P.T. Interactions in aqueous nonelectrolyte systens. Gibbs energy of interaction of the ether group with hydroxyl group and amide group. J. Solut. Chem. 1985. Vol. 14. N 11. P. 781-794.

87. Tasker I.R., Wood R.H. Enthalpies of dilution of aqueous solution of amides and alcohols. J. Solut. Chem. 1982. Vol. 11. N 5. P. 295-308.

88. Zielenkiewicz A. Heat of dilution of aqueous mixtures of No-alkylated amides at 313.15 K. Thermochim. Acta. 1984. Vol. 79. P. 371-376.

89. Grolier J.P., Spitzer J.J., Wood R.H., Tasker I.R. Freezing temperatures and enthalpies of dilution of aqueous solution of amides. Gibbs energies and enthalpies of interaction oh the No,No-dimethylamide group in aque-ous solutions. J. Solut. Chem. 1985. Vol. 14. N 6. P. 393-405.

90. Batov D.V., Batov D.D. Solvation of formic and acetic acid amides in water-glycerol mixture. Additivity of thermochemical characteristics of solutions. Zhurnal strukturnoi khimii. 2005. Vol. 46. N 2. P. 293-302 (in Rus-sian).

91. Batov D.V. Additive scheme for calculating the properties of solutions of organic compounds. Limiting partial molar volumes of alkanols in aqueous solution. Zhurnal prikladnoi khimii. 2007. Vol. 80. N 3. P. 435-439 (in Russian).

92. Franks F., Smith H.T. Precision densities of dilute aqueous solution of the isomeric butanols. J. Chem. Eng. Data. 1968. Vol. 13. N 4. P. 538-547.

93. Hoiland H. Partial molal volumes of alcohols in propylene carbonate at 25°C. J. Solut. Chem. 1976. Vol. 5. N 11. P. 773-780.

94. Nakajima T., Komatsu T., Nakagawa T. Apparent Molal Volumes and Adiabatic Compressibilities of n-Al-kanols and α,ω-Alkane Diols in Dilute Aqueous Solutions at 5, 25, and 45°C. I. Apparent Molal Volumes. Bull. Chem. Soc. Japan. 1975. Vol. 48. N 3. P. 783-787.

95. Marsh K.N., Richards A.E. Excess enthalpies for ethanol + water at 10-K intervals from 278.15 to 318.15 K. Austr. J. Chem. 1980. Vol. 33. N 10. P. 2121-2132.

96. Cabani S., Conti G., Lepori I. Volumetric properties of aqueous solutions of organic compounds. III. Aliphatic secondary alcohols, cyclic alcohols, primary, secondary, and tertiary amines. J. Phys. Chem. 1974. Vol. 78. N 10. P. 1030-1034.

97. Panov M.Yu., Belousov V.P., Morachevskii A.G. Chemistry and thermodynamics of solutions. Leningrad: LSU Publ., 1977. N 4. P. 158-213 (in Russian).

98. Jolicocur C., Lacroix G. Thermodynamic properties of aqueous organic solutes in relation to their structure. Part III. Apparent molal volumes and heats capacities of low molecular weight alcohols and polyols. Canad. J. Chem. 1976. Vol. 54. N 4. P. 624-631.

99. Larkin J.A., Pemberton R.G. Int. Conf. Chem. Thermodyn. 3rd. Baden. 3-7 Sept, 1973. Vol. 3. P. 163.

100. Baratov A.N., Korol'chenko A.Ya., Kravchuk G.N. Explosion hazards of substances and materials and means of extinguishing them: Reference Book. Vol. 1/2. Moscow: Khimiya, 1990. 496 p. (in Russian).

101. Baratov A.N., Korol'chenko A.Ya., Kravchuk G.N. Fire and explosion safety of substances and materials and means of extinguishing them: Reference Book. Vol. 2/2. Moscow: Khimiya, 1990. 384 p. (in Russian).

102. Korol'chenko, A.Ya., Korolchenko, D.A. Explosion hazards of substances and materials and means of extinguishing them: Reference Book. In 2 parts. 2 ed., revised and extended. Moscow: Pozhnauka, 2004. Pt. 1. 713 p. (in Russian).

103. Korolchenko, A.Ya., Korol'chenko, D A. Explosion hazards of substances and materials and means of extinguishing them: Reference Book. In 2 parts. 2 ed., revised and extended. Moscow: Pozhnauka, 2004. Pt. 2. 774 p. (in Russian).

104. GOST 12.1.044-89. Occupational safety standards system. Fire and explosion hazard of substances and materials. Nomenclature of indices and methods of their determination (in Russian).

105. Calculation of basic indicators of fire and explosion hazard of substances and materials: Guidebook. Moscow: VNIIPO, 2002. 77 p. (in Russian).

106. Alekseev S.G., Barbin N.M., Alekseev K.S., Orlov S.A. Relation of fire hazard indicators to chemical structure. I. Alkanols. Pozharovzryvobezopasnost'. 2010. Vol. 19. N 5. P. 23-30 (in Russian).

107. Alekseev S.G., Barbin N.M., Alekseev K.S., Orlov, S.A. Relation of fire hazards to chemical structure. II. Ketones (pt. 1). Pozharovzryvobezopasnost'. 2011. Vol. 20. N 6. P. 8-15 (in Russian).

108. Alekseev S.G., Barbin N.M., Alekseev K.S., Orlov S.A. Relation of fire hazard indicators to chemical structure. III. Ketones (pt. 2).] Pozharovzryvobezopasnost'. 2011. Vol. 20. N 7. P. 8-13 (in Russian).

109. Alekseev S.G., Barbin N.M., Alekseev K.S., Orlov S.A Relation of fire hazard indicators to chemical structure. IV. Simple esters. Pozharovzryvobezopasnost'. 2011. Vol. 20. N 9. P. 9-16 (in Russian).

110. Alekseev K.S., Barbin N.M., Alekseev S.G. Relation of fire hazard indicators to chemical structure. V. Carboxylic acids. Pozharovzryvobezopasnost'. 2012. Vol. 21. N 7. P. 35-46 (in Russian).

111. Alekseev K.S., Barbin N.M., Alekseev S.G. Relation of fire hazard indicators to chemical structure. VI. Aldehydes. Pozharovzryvobezopasnost'. 2012. Vol. 21. N 9. P. 29-37 (in Russian).

112. Alekseev S.G., Barbin N.M., Smirnov V.V. Relationship of fire hazard indicators to chemical structure. Nitroalkanes. Pozharovzryvobezopasnost'. 2012. Vol. 21. N 12. P. 22-24 (in Russian).

113. Alekseev K.S., Alekseev S.G., Barbin N.M. Relation of fire hazard indicators to chemical structure. VIII. Complex esters. (pt. I).] Pozharovzryvobezopasnost'. 2013. Vol. 22. N 1. P. 31-57 (in Russian).

114. Batov D.V., Mochalova T.A., Petrov A.V. Additive group techniques for calculating the flash point of alcohols, ketones and esters. Rus. J. App. Chem. 2011. Vol. 84. N 1. P. 54-59.

115. Batov D.V., Mochalova T.A., Petrov A.V. Description and prediction of flash temperatures of esters within the additive-group method. Pozharovzryvobezopasnost'. 2010. Vol. 19. N 2. P. 15-18 (in Russian).

116. Batov D.V. The use of additive-group method for the analysis, systematization and prediction of fire hazard indicators for flammable liquids. Rossiiskii khimicheskii zhurnal (Zhurnal Rosssiiskogo khimicheskogo obschestva im. D.I. Mendeleeva). 2014. Vol. LVIII. N 2. P. 4-14 (in Russian).

117. Batov, D.V., Mochalova, T.A., Storonkina, O.E. Modification of additive-group method for description of fire hazard indicators of limiting hydrocarbons: flash and auto-ignition temperatures, enthalpy of vaporization. Pozharovzryvobezopasnost'. 2017. Vol. 26. N 5. P. 21-28 (in Russian).

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