Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl State Technical University (Kafedra «Tehnologiya stroitel'nogo proizvodstva»., Professor)
Yaroslavl, Yaroslavl, Russian Federation
The article analyses literature sources and general classification of surface-active substances (surfactants). The analysis explains the scientific interest in the development of new high molecular weight and polymeric compounds changing the surface tension on the prase boundaries. The article gives examples of the use of polymeric surfactants in various areas for the chemical industry and in construction (modified additives in concrete, protective compositions and paint compositions) itself. Despite the market of synthesised polymeric surfactants has not undergone global changes in recent years, the modern stage of scientific development has revealed a range of promising modifiers. Adding these modifiers to the systems provides a predictable effect of creating tenacious compositions with good adhesion to the surface of building materials and structures, as well as obtaining water-resistant coatings on the basis of such compositions.
polymeric surface-active substances, high molecular weight compounds, critical micelle formation concentration, modifying additives, paint dispersants, strength and adhesion of compositions, water-resistant coatings
1. Neudachina L.K., Petrova Y.S. Application of surfactants in analysis: [textbook]. Ekaterinburg: Izd-v Ural. un-ta, 2017. 76 p. (In Russian).
2. Mansuraeva L.M. Surface-active substances: properties and application // Vestnik magistratury [Bulletin of Magistracy]. 2022. No. 2-1. Pp. 30-35 (in Russian).
3. Abramzon A.A. Surface-active substances: Properties and application. 2nd edition, revision and additions. L.: Khimiya, 1981. 304 p. (In Russian).
4. Krysin M.Yu., Verezhnikov V.N., Germasheva I.I. Colloidal chemistry of surfactants: textbook. SPb: Lan, 2015. 304 p. (In Russian).
5. Voyutsky, S.S. Course of colloid chemistry. Ed. 2nd, revision and supplement. M. : Khimiya, 1975. 512 p. (In Russian).
6. Frolov, Yu.G., Course of colloid chemistry. Surface phenomena and disperse systems: textbook for universities. M. : Alliance, 2004. 464 p. (In Russian).
7. Holmberg K., Jensson B., Kronberg B., Lindman B. Surfactants and polymers in aqueous solutions. M. : Binom. Laboratory of Knowledge, 2013.
8. Shtykov S.N., Goryacheva I.Yu., Shtykova L.S. Mitselly i mikroemul'sii v razdelenii i kontsentrirovanii [Micelles and microemulsions in separation and concentration] // Zhurn. analit. khimii [Zhurn. analytical chemistry]. 2003. Vol. 58, no. 7. Pp. 732-733 (in Russian).
9. Shtykov, S. N. Surfactants in analysis: Progress and development trends // Journal of Analytical Chemistry. 2000. Vol. 55, No. 7. Pp. 608-614. DOI:https://doi.org/10.1007/BF02827992.
10. Junquera E., Tardajos G., Aicart E. Effect of the presence of beta-cyclodextrin on the micellization process of sodium dodecyl sulfate or sodium perfluorooctanoate in water // Langmuir. 1993. Vol. 9, no. 5. Pp. 1213–1219. DOI:https://doi.org/10.1021/la00029a0.
11. Umlong I.M., Ismail K. Micellization behaviour of sodium dodecyl sulfate in different electrolyte media // Colloids and Surfaces A: Physicochem. Eng. Aspects. 2007. Vol. 299, no. 3. Pp. 8–14. DOI:https://doi.org/10.1016/j.colsurfa.2006.11.010.
12. Soniaa S.S., Panjabib S.H., Sastryaa N.V. Effect of non-electrolyte additives on micellization and clouding behavior of silicone surfactant in aqueous solutions // Colloids and Surfaces A: Physicochem. Eng. Aspects. 2011. Vol. 377, no. 3. Pp. 205-211. DOI:https://doi.org/10.1016/j.colsurfa.2010.12.048.
13. Mohajeri Eh., Noudeh Gh.D. Effect of temperature on the critical micelle concentration and micellization thermodynamic of nonionic surfactants: Polyoxyethylene sorbitan fatty acid esters // E-Journal of Chemistry. 2012. V. 9, no. 4. Pp. 2268–2274. DOI:https://doi.org/10.1155/2012/961739.
14. Friedrichsberg D.A. Course of colloid chemistry. Textbook for universities. 2nd ed., rev. and ext. L. : Khimiya, 1984. 368 p. (In Russian).
15. Akhmedov K.S. Water-soluble polymers and their interaction with disperse systems. Tashkent: ‘FAN’, 1969. 250 p. (In Russian).
16. Pletnev M.Yu. Surface-active substances and compositions. Reference book. /Edited by M.Y. Pletnev. Moscow: LLC ‘Firma Klavel’, 2002. 768 p. (In Russian).
17. Shchukin E.D., Pertsov A.V., Amelina E.A. Colloidal chemistry: Textbook for universities and chemical engineering universities. 3rd ed., rev. and ext. M. : Vysh. shk., 2004. 445 p. (In Russian).
18. Semchikov Yu.D. High-molecular compounds: textbook for students of higher professional education institutions. 5th ed., st. M. : Izd. centre ‘Academy’, 2010. 368 p. (In Russian).
19. Chernov A.A. Regulirovanie gruppovogo uglevodorodnogo sostava gudronov – syr'ya neftetekhnologicheskikh protsessov [Regulation of group hydrocarbon composition of tar sands - feedstock of oil-technological processes] // Neftepererabotka i neftekhimiya [Oil refining and petrochemistry]. 2004. No. 10. Pp. 17-19. (In Russian).
20. Shrubok A.O. Okislennye bitumy iz modifitsirovannogo syr'ya [Oxidised bitumen of modified raw materials] // Tr. BGTU [Proceedings of BSTU]. 2012, No. 4. Pp. 92-95.
21. Fedulov A.A. Application of surface-active substances (stabilisers) for improving the properties of cohesive soils in conditions of road construction: dissertation of Cand. of Tech. Sciences: 05.23.11 / Fedulov Andrey A. M., 2005. 165 p. (In Russian).
22. Yakimovich I.V. Asphalt concrete with adhesion additive DAD-1: dissertation of Cand. of Tech. Sciences: 05.23.05 / Igor Valentinovich Yakimovich. Belgorod, 2009. 178 p. (In Russian).
23. Akhmadova Kh.Kh. et al. Osnovnye sposoby modifikatsii bitumov razlichnymi dobavkami [Main ways of bitumen modification with different additives] // Vestnik GGNTU. Tekhnicheskie nauki [Vestnik of GGNTU. Technical Sciences]. Vol. XV. No. 3 (17). 2019. Pp. 42-57 (In Russian).
24. Ramachadran V.S., Feldman R.F., Kollepardi M. [et al.] Additives in concrete: reference manual. Stroyizdat, 1988. 575 p. (In Russian).
25. Schramm Laurier L., Stasiukb Elaine N., Marangoni D. Gerrard. Surfactants and their applications // Annu. Rep. Prog. Chem. 2003. Vol. 99. Pp. 3–48. DOI:https://doi.org/10.1039/B208499F.
26. GOST 24211-2008. Additives for concrete and mortars. Publ. 01.01.2011. (In Russian).
27. Pat. RU 2360880. Superplasticiser of high initial strength / Clemente Paolo, Ferrari Giorgio, Gamba Mariele, Pistolesi Carlo et al. Publ. 10.07 2009.
28. Pat. RU 2390530. Additive to concrete and mortar / Izumi Tatsuo, Zanders Karsten, Jansen-Bockting Marion, Dikti Stefan. Publ. 10.06.2010.
29. Ferrari L., Kaufmann J., Winnefeld F., Plank J. Multi-method approach to study influence of superplasticizers on cement suspensions // Cement and Concrete Research. 41. DOI: https://doi.org/1058https://doi.org/10.1016/j.cemconres.2011.06.010.
30. Agarwal S.K., Masood I., Malhotra S.K. Compatibility of superplasticizers with different cements // Constr. Build. Mater. 2000. Vol. 14, No. 5. Pp. 253–259. DOI:https://doi.org/10.1016/S0950-0618(00)00025-8.
31. Prince W., Espagne M., Aitcin P.-C. Ettringite formation: a crucial step in cement superplasticizer compatibility // Cem. Concr. Res. 2003. Vol. 33, No. 5. Pp. 635–641.
32. Nikinamubanzi P.-C., Aitcin P.-C. Cement and superplasticizer combinations: compatibility and robustness // Com. Concr. Agg. 2004. Vol. 26, No. 2. Pp. 102–109. DOI:https://doi.org/10.1520/CCA12329.
33. Brock T., Groteklaus M., Mischke P. European Guide to Paint and Coatings. Moscow: Paint-Media Ltd., 2004. 548 p. (In Russian).
34. Bielman J. Additives for Coatings. Willey, VCN, 2001. P. 130.
35. Grigoriev I.V., Miftakhov E.N., Mustafina S.A. Matematicheskoe modelirovanie protsessa polimerizatsii stirola s maleinovym angidridom [Mathematical modelling of the process of styrene polymerisation with maleic anhydride] // Vestnik Tekhnologicheskogo universiteta [Bulletin of Technological University]. 2015. Vol. 18, No. 15. Pp. 211-216 (in Russian).
36. Staroverova O.S. Epoxyether modification of polymeric materials for paint and varnish coatings: dissertation of Cand. of Chem. Sciences: 02.00.06 / Staroverova Olga Sergeevna. - Yaroslavl, 2014. - 118 p. (In Russian).
37. Pat. 0292702B1 Composition containing dispersed pigment / Harunori G., Hisao K., Hiroyoshi K. Publ. 23.12.85.
38. Manerov E.V. Influence of polymeric surfactants on formation and properties of polyether-melamine-formaldehyde compositions: dissertation of Cand. of Tech. Sciences: 02.00.06 / Evgeny Vladimirovich Manerov. Yaroslavl, 2012. 155 p. (In Russian).
39. Shevchenko N.M. Rheological and dispersing additives used in paint and varnish materials. M. : NIITEKHIM, 1990. 34 p. (In Russian).
40. Leiko V.V., Stepanova N. A., Kupriyanov V. D., Korsakov V. G. Rheological characteristics of barium titanate suspensions in butadiene-nitrile rubber solutions // Kolloidnyj Zhurnal. 1995. Vol. 57, No. 3. P. 364-367.
41. Lipatov Yu.S. Physico-chemical bases of polymer filling. M. : Nauka. 1991. 260 p. (In Russian).
42. Baenkevich V.V., Lavrischev L.P., Tsyurupa N.N. Reologicheskii sposob opredeleniya kriticheskoi kontsentratsii pigmenta [Rheological method of determining the critical concentration of pigment] // LKM i ikh primenenie [Paint and varnish materials and their application]. 1975. No. 3. Pp. 61-62 (in Russian).
43. Pat. 4347285 of USA / Batdorf Vernon H. Publ. 1982.
44. Primachenko O.N., Pavlyuchenko V.N., Gagarina K.A. [et al.] Antistaticheskie lateksnye pokrytiya na osnove aminosoderzhashchikh sopolimerov [Antistatic latex coatings based on amine-containing copolymers] // Zhurnal prikladnoi khimii [Journal of Applied Chemistry]. 2000. Vol. 73, No. 10. Pp. 1713-1719 (in Russian).
45. Primachenko O.N, Sorochinskaya O. V., Pavlyuchenko V. N. [et al.] Compound latexes for antistatic coatings // Russian Journal of Applied Chemistry. 2002. Vol. 75, No. 10. P. 1705-1708. DOI:https://doi.org/10.1023/A:1022256624472.
46. Pat. 4737575 of USA / Blount David H. Publ. 1988.
47. Grigoriev P.N., Matveev M.A. Soluble glass. Moscow: Promstroizdat. 1956. 444 p. (In Russian).
48. Panov V.P., Elkhova N.N., Strelkov V.P., Vakhterov G.N. Copyright certificate 1158539 USSR // Bul. 1985. No. 20 (in Russian).
49. Pavlov V.I., Zbanatsky N.L., Veselovsky N.A. Vliyanie silikatnogo modulya zhidkogo stekla na prochnost' otverzhdennykh kompozitsii poliizotsianata [Influence of silicate module of liquid glass on the strength of cured polyisocyanate compositions] // Plastmassy [Plastics]. 1988. Issue. 10. Pp. 15-17 (in Russian).
50. Maistrenko A.A., Glukhovsky V.D., Runova R.F., Staroselsky S.Y., Kavalerova E.S. Copyright certificate 1257080 USSR // Bul. 1986. No. 34. (In Russian).
51. Albertinsky G.L., Delgadillo H.E., Agafonov G.I., Verkholantsev V.V. Vliyanie PAV na svoistva vodnykh rastvorov silikatov shchelochnykh metallov [Effect of surfactants on the properties of aqueous solutions of alkali metal silicates] / LKM i ikh primenenie [Paint and varnish materials and their application]. 1988. No. 2. Pp. 13-15 (in Russian).
52. Albertinsky L.G., Delgadillo H.E., Agafonov G.I., Verkholantsev V.V. Vliyanie PAV na nekotorye svoistva zhidkikh stekol [Influence of surfactants on some properties of liquid glasses] / LKM i ikh primenenie [Paint and varnish materials and their application]. 1988. No. 5. Pp. 17-18 (in Russian).
