Ярославль, Ярославская область, Россия
Ярославль, Ярославская область, Россия
с 01.01.1974 по настоящее время
Ярославль, Ярославская область, Россия
The purpose of the article is to study the effect of mechanochemical processing (MCP) of vulcanising group components on the properties of rubber compound and natural rubber vulcanizate containing technocarbon N 330 with a small addition of high-dispersed silica filler. The processing of both individual components: zinc oxide as accelerator and all components of sulphuric curing group increases the speed and degree of rubber structuring during the main period of vulcanization, reduces the tendency of rubber to reversion at the postvulcanization stage. This increases both the conditional stress and tensile strength of rubber.
natural rubber, vulcanising group, mechanochemical processing, vulcanisation characteristics, vulcanisate, deformation strength properties
1. Avakumov E.G. Mechanical methods of activation of chemical processes. Novosibirsk: Nauka, 1989. 306 p. (in Russian).
2. Kajdas C. General Approach to Mechanochemistry and its Relation to Tribochemistry. Chapter 11. 2013. 240 p. DOI:https://doi.org/10.5772/50507.
3. Tricker A.W. Hot spot generation, reactivity, and decay in mechanochemical reactors. Chemical Engineering Journal. 2020. V. 382. P. 122954. DOI: 10.1002 / advs.201700132.
4. Kajdas C. Mechanical Activation of Chemical Process. Materials Sciences and Applications. 2015. N 6. P. 60 67. DOI:https://doi.org/10.4236/msa.2015.61008.
5. Barton S.S. Acidic and basic sites on the surface of porous carbon. Carbon. 1997. V. 35. N 9. P. 1361–1366.
6. Razumovskii S.D. Mechanochemical methods of activating processes of biomass pretreatment. Catalysis in Industry. 2011. V. 3. P. 23-27. DOI:https://doi.org/10.1134/S2070050411010107.
7. Juhász A.Z. Aspects of mechanochemical activation in terms of comminution theory. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1998. V. 141. P. 449-462.
8. Boldyrev V.V. Fundamental Bases of Mechanical Activation, Mechanosynthesis and Mechanochemical Technologies. Novosibirsk: Publishing house of Siberian Branch of RAS, 2009. 343 p. (in Russian).
9. Moiseevskaya G.V., Shpakov M.Y., Razdyakonova T.N. About efficiency of mechanoactivation of shungite filler for taurite TS-D rubber. P. 1. Properties of shungite powder. Kauchuk i resina. 2012. N 6. P. 14-16 (in Russian).
10. Moiseevskaya G.V., Shpakov M.Y., Razdyakonova T.N. About efficiency of mechanoactivation of shungite filler for taurite TS-D rubber. P. 2. The results of tests of shungite fillers in rubber mixtures. Kauchuk i resina. 2012. N 6. P. 16-20 (in Russian).
11. Petrova N.N. Mechanochemical activation of natural zeolites as a method of obtaining polyfunctional rubber modifiers. Kauchuk i resina. 2008. N 4. P. 17-22 (in Russian).
12. Makarov V.M., Solovieva O.Yu., Nikitina E.L. Effect of mechanochemical treatment of ingredients on structure and properties of rubber mixtures and rubbers on basisof 1,4-cis-polyisoprene. Izvestiya vuzov. Himiya i himicheskaya tekhnologiya. 2020. V. 63. N 5. P. 89-93. DOI:https://doi.org/10.6060/ivkkt.20206305.6162 (in Russian).
13. Makhlis F.A., Fedyukin D.L. Terminological Handbook for Rubber. Moscow: Chemistry, 1989. 400 p. (in Russian).
14. Kandyrin K.L., Sedov A.S. Application of RPA device for evaluation of properties of filled rubbers. Voprosy prakticheskoj tekhnologii izgotovleniya shin. 2010. N 1 (50). P. 93-100 (in Russian).
15. Pichugin A.M. Material science aspects of making tyre rubbers. Moscow: Mashinostroenie, 2008. 383 p. (in Russian).
16. Solovieva O.Y., Vetoshkin A.B., Gudkov S.V., Nikitina E.L. Modification of mixtures based on ethylenepropylene rubber and silicon acid filler. Izvestiya vuzov. Himiya i himicheskaya tekhnologiya. 2021. V. 64. N 2. P. 81-86. URL: https://doi.org/10.6060/ivkkt.20216402.6309 (in Russian).
17. Markelov V.G., Solovyov M.E. Vulcanizationof Thick-Walled Rubber Products Simulation. Izvestiya vuzov. Himiya i himicheskaya tekhnologiya. 2007. V. 50. N 4. P. 95-98 (in Russian).
18. Markelov V.G., Solovyov M.E. Model Parametres Estimation of Tire Rubber Curing Reaction in the Frame of Formal Kinetic Scheme. Izvestiya vuzov. Himiya i himicheskaya tekhnologiya. 2008. V. 51. N 4. P. 40-41 (in Russian).