Ivanovo, Ivanovo, Russian Federation
student
Ivanovo, Ivanovo, Russian Federation
Sintezirovany mezo-tetrakis(1’-metil-pirid-4-il)porfirin tetratozilat i mezo-tetrakis(1’-metil-karboksimetilpirid-4-il)porfirin tetrabromid. Porfirin-ligandy oharakterizovany metodami elektronnoy i 1H YaMR spektroskopii. Opredeleno ponizhenie temperatury zamerzaniya (ΔTzam) vodnyh rastvorov porfirinov, a takzhe model'noy N-metil-piridinievoy soli (1-metil-piridiniy iodid). Poluchennye eksperimental'nye znacheniya ΔTz ispol'zovany pri opredelenii izotonicheskogo koefficienta. Poluchennye rezul'taty svidetel'stvuyut o tom, chto v ukazannoy oblasti koncentraciy v razbavlennyh rastvorah, soedineniya prakticheski polnost'yu dissociirovany.
Vodorastvorimye tetrapiridilporfiriny, voda, izotonicheskiy koefficient, krioskopiya
1. Berezin B.D. Porfiriny: spektroskopiya, elektrohimiya, primenenie / pod red. N.S. Enikolopyana. M.: Nauka, 1985. 333 s.
2. Abramov I.G., Baklagin V.L., Makarova E.S., Kleykova D.E. Ispol'zovanie azotsoderzhaschih geterociklicheskih O-, i S-nukleofilov v reakciyah s 4-nitroftalonitrilom i 4-brom-5-nitroftalonitrilom katalizatorov // Ot himii k tehnologii shag za shagom. 2021, T. 2, vyp. 4. S. 43-49. URL: http://chemintech.ru/index.php/tor/2021-2-4
3. Koifman O.I. Macroheterocyclic sompounds – a key building block in new functional materials and molecular devices // Macroheterocycles. 2020. Vol. 13. P. 311-467. DOI:https://doi.org/10.6060/mhc200814k.
4. Masa J., Ozoemena K., Schuhmann W., Zagal J.H. Oxygen reduction reaction using N4-metallomacrocyclic catalysts: fundamentals on rational catalyst design // J. Porphyrins and Phtalocyanines. 2012. Vol. 16. P. 761 784. DOI:https://doi.org/10.1142/S1088424612300091.
5. Kuzmin S.M., Chulovskaya S.A., Parfenyuk V.I., Koifman O.I. Poly-5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin as a material for photovoltaic devices // Mendeleev Communications. 2020. Vol. 30, no. 6. P. 777-780. DOI:https://doi.org/10.1016/j.mencom.2020.11.030.
6. Zamadar M., Orr Ch., Uherek M. Water Soluble Cationic Porphyrin Sensor for Detection of Hg2+, Pb2+, Cd2+ and Cu2+ // Journal of Sensors. 2016. Vol. 216. DOI:https://doi.org/10.1155/2016/1905454.
7. Grin M.A., Suvorov N.V., Mironov A.F. Natural chlorins as a promising platform for creating targeted theranostics in oncology // Mendeleev Commun. 2020. Vol. 30, no. 4. P. 406-418. DOI:https://doi.org/10.1016/j.mencom.2020.07.003.
8. Kustov A.V., Berezin D.B., Strel'nikov A.I., Lapochkina N.P. Protivoopuholevaya i antimikrobnaya fotodinamicheskaya terapiya: mehanizmy, misheni, kliniko-laboratornye issledovaniya / pod red. A.K. prof. Gagua. M.: Largo, 2020. 108 s.
9. Giancola C., Caterino M., D'Aria F., Kustov A.V., Belykh D.V., Khudyaeva I.S., Starseva O.M., Berezin D.B., Pylina Y.I., Usacheva T., Amato J. Selective binding of a bioactive porphyrin-based photosensitizer to the G-quadruplex from the KRAS oncogene promoter // International Journal of Biological Macromole-cules. 2020. Vol. 145. P. 244-251. DOI:https://doi.org/10.1016/j.ijbiomac.2019.12.152.
10. Kruk N.N. Stroenie i opticheskie svoystva tetrapirrol'nyh soedineniy. Minsk: BGTU, 2019. 216 s.
11. Gu J, Peng Y, Zhou T, Ma J., Pang H., Yamauchi Y. Porphyrin-based framework materials for energy conversion // Nano Research Energy. 2022. Vol. 1. e9120009. DOI:https://doi.org/10.26599/NRE.2022.9120009.
12. Berezina N.M., Berezin M.B., Semeikin A.S. Solvation interactions and photostability of tetrakis(1-methylpyridyl)porphyrin derivatives // Journal of Molecular Liquids. 2019. Vol. 290. DOI:https://doi.org/10.1016/j.molliq.2019.111196.
13. Amorim C. F., Iglesias B. A., Pinheiro T. R., Lacerda L.E., Sokolonski A.R., Pedreira B.O., Moreira K.S., Burgo L.T.A., Meyer R., Azevedo V., Portela R.W. Photodynamic inactivation of different Candida species and inhibition of biofilm formation induced by water-soluble porphyrins // Photodiagnosis and Photodynamic Therapy. 2023. Vol. 42, no. 103343. DOI:https://doi.org/10.1016/j.pdpdt.2023.103343.
14. Fialkov Yu. Ya. Rastvoritel' kak sredstvo upravleniya himicheskim processom. L.: Himiya, 1990. 240 s.
15. Himanshu P., Khare A. Cryoscopic studies of α-amino acids in water // Journal of Molecular Liquids. 2005, Vol. 122. P. 61-64.
16. Berezina N.M., Berezin M.B., Do Ngok Minh, Bazanov M.I. Solvation and coordination interactions of tetrapyridylporphyrin in aqueous solutions. Thermal stability // Russian Journal of General Chemistry. 2017. Vol. 87, no. 3. P. 639-650. DOI:https://doi.org/10.1134/S1070363217030422.
17. Berezina N.M., Bazanov M.I., Semeykin A.S., Berezin M.B. Nekotorye fiziko-himicheskie svoystva kompleksonov, proizvodnyh tetrapiridilporfina // Zhurnal fizicheskoy himii. 2009. T. 83, № 5. S. 903-910.
18. Berezina N.M., Bazanov M.I. Semeikin A.S., Berezin M.B. The physicochemical properties of complexones, tetrapyridylporphin derivatives // Russian Journal of Physical Chemistry. 2009. Vol. 83, no. 5. P. 785-791. DOI:https://doi.org/10.1134/S0036024409050185.
