Ivanovo, Ivanovo, Russian Federation
Ivanovo, Ivanovo, Russian Federation
Sintezirovany mezo-tetrakis(1’-metil-pirid-4-il)porfirin tetratozilat i mezo-tetrakis(1’-metil-karboksimetilpirid-4-il)porfirin tetrabromid. Porfirin-ligandy oharakterizovany metodami elektronnoy i 1H YaMR spektroskopii. Opredeleno ponizhenie temperatury zamerzaniya (ΔTzam) vodnyh rastvorov porfirinov, a takzhe model'noy N-metil-piridinievoy soli (1-metil-piridiniy iodid). Poluchennye eksperimental'nye znacheniya ΔTz ispol'zovany pri opredelenii izotonicheskogo koefficienta. Poluchennye rezul'taty svidetel'stvuyut o tom, chto v ukazannoy oblasti koncentraciy v razbavlennyh rastvorah, soedineniya prakticheski polnost'yu dissociirovany.
Vodorastvorimye tetrapiridilporfiriny, voda, izotonicheskiy koefficient, krioskopiya
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