CATALYTIC OXIDATION OF FLUORINATED AROMATIC COMPOUNDS BY HYDROGEN PEROXIDE IN THE PRESENCE OF Μ-NITRIDODIMERIC IRON PHTHALOCYANINATE
Abstract and keywords
Abstract (English):
It has been shown that µ-nitrido(bis) iron phthalocyaninate is an effective catalyst for the oxidation of fluoroaromatic compounds with hydrogen peroxide, including such difficult to oxidized substrates as hexafluorobenzene and pentafluoropyridine. The main fluoride containing product is inorganic fluoride. It has been found that this catalyst, when supported on a graphite, exhibits high stability and can be used after simple regeneration.

Keywords:
oxidation, catalytic defluorination, iron phthalocyaninate, homogeneous and heterogeneous catalysis, hydrogen peroxide
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References

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