Ярославль, Ярославская область, Россия
студент
Ярославль, Ярославская область, Россия
Ярославль, Ярославская область, Россия
Ярославский государственный технический университет
аспирант
Ярославль, Россия
сотрудник
Ярославль, Ярославская область, Россия
Казань, Республика Татарстан, Россия
УДК 547.534.1 Этилбензол
The article describes a study of basic principles of aerobic liquid-phase oxidation of ethylbenzene to hydroperoxide. According to the research, the use of phthalimide catalysts (N-hydroxyphthalimide and its derivatives) can increase the oxidation rate of this hydrocarbon by 1.5-2 times compared with initiators of different nature. At the same time, high selectivity of target hydroperoxide formation is still present - about 90%. The authors recommend conditions for oxidation of ethylbenzene in the presence of phthalimide catalysts based on experimental data. The results obtained can be used to improve the technology for co-production of propylene oxide and styrene, valuable products of the main chemical and petrochemical synthesis.
ethylbenzene, liquid-phase aerobic oxidation, ethylbenzene hy-droperoxide, N-hydroxyphthalimide, phthalimide catalysts, propylene oxide, styrene
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