Аннотация (русский):
В обзоре обобщены литературные и собственные экспериментальные результаты по синтезу, особенностям структуры, спектральным, кислотно-основным и координационным свойствам ароматических макрогетероциклов корролов, а также кратко рассмотрены перспективы их практического применения. Продемонстрирована тесная взаимосвязь свойств корролов и особенностей их геометрической и π-электронной структуры. Показано, что при, казалось бы, несущественном изменении структуры по сравнению с наиболее изученным классом тетрапиррольных макрогетероциклических соединений – порфиринами, корролы обладают целым рядом особенностей и уникальных характеристик.

Ключевые слова:
тетрапиррольные макрогетероциклические соединения; порфирины; корролы; синтез; спектральные характеристики; кислотно-основные и координационные свойства; металлокомплексы; катализ; фотодинамическая терапия

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176. Aviv I., Gross Z. Iron porphyrins catalyse the synthesis of non-protected amino acid esters from ammonia and diazoacetates. Chem. Commun. 2006. P. 4477–4479.

177. Simkhovich L., Gross Z. Iron(IV) corroles are potent catalysts for aziridination of olefins by chloramine-T. Tetrahedron Lett. 2001. V. 42. P. 8089–8092.

178. Mairena M.A., Diaz-Requejo M.M., Belderrain T.R., Nicasio M.C., Trofimenko S., Perez P.J. Copper-homoscorpionate complexes as very active catalysts for the olefin aziridination reaction. Organometallics. 2004. V. 23. P. 253–256.

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